- 🐎 José Antonio Páez (1830–1835; 1839–1843; 1861–1863)
- 🎓 José María Vargas (1835–1836)
- ✍️ José María Carreño (interino, 1836)
- 🎖️ Carlos Soublette (1837–1839; 1843–1847)
- 🔔 José Tadeo Monagas (1847–1851; 1855–1858)
- 📜 José Gregorio Monagas (1851–1855)
- ⚖️ Pedro Gual Escandón (interino, 1858)
- 🗡️ Julián Castro (1858–1859)
- 🛢️ Antonio Guzmán Blanco (1870–1877; 1879–1884; 1886–1887)
- 🌿 Francisco Linares Alcántara (1877–1878)
- 🔧 José Gregorio Valera (1878–1879)
- 🔄 Joaquín Crespo (1884–1886; 1892–1898)
- ✒️ Cipriano Castro (1899–1908)
- 👑 Juan Vicente Gómez (1908–1935)
- ⚙️ Eleazar López Contreras (1935–1941)
- 🌱 Isaías Medina Angarita (1941–1945)
- 🗳️ Rómulo Betancourt (1945–1948; 1959–1964)
- 📚 Rómulo Gallegos (1948)
- 🛡️ Carlos Delgado Chalbaud (1948–1950)
- 🎖️ Germán Suárez Flamerich (1950–1952)
- 🔨 Marcos Pérez Jiménez (1952–1958)
- 🔄 Edgar Sanabria (interino, 1958–1959)
- 🎸 Raúl Leoni (1964–1969)
- 🌴 Rafael Caldera (1969–1974; 1994–1999)
- 🛢️ Carlos Andrés Pérez (1974–1979; 1989–1993)
- 📈 Luis Herrera Campins (1979–1984)
- 💼 Jaime Lusinchi (1984–1989)
- 🔄 Ramón José Velásquez (interino, 1993–1994)
- 🌹 Hugo Chávez (1999–2013)
- 🏛️ Nicolás Maduro (2013–presente)